Title : Turning trash to treasure: Rice straw derived biopolymer for sustainable applications
Abstract:
In the present study, cellulose biopolymer was isolated from rice straw by alkali bleaching pretreatment, and converted into carboxymethylcellulose (CMC) biopolymer by two step carboxymethylation reaction, i.e. alkalization followed by etherification. The synthesis conditions for this chemical modification, such as the solvent medium, NaOH and sodium monochloroacetate concentration were optimized to obtain CMC with high degree of substitution. The infrared spectroscopic studies of the synthesized CMC clearly showed an increased intensity of C=O bond at 1600 cm-1, which is an indication of successful carboxymethylation of –OH bonds of anhydroglucose units. The obtained CMC biopolymer was further reinforced with bentonite clay particles. The composite matrix showed good sorption capacity for methylene blue dye contaminant in aqueous media, showing prospective application in water remediation. Furthermore, the formed biopolymer was tested for agricultural applications as a slow release fertilizer. Therefore, this study shows that the lignocellulosic agrowaste is a rich source of cellulose, and its derivative such as the CMC possesses the potential to realize the waste to wealth sustainability goal.

